|
|
acetyl-CoA + [acyl-carrier_protein] <=> CoA + acetyl-[acyl-carrier_protein]
|
2.3.1
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
2.7.8.7
holo-[acyl-carrier-protein] synthase
|
–
–
–
–
–
–
–
|
BMK
|
| |
BRENDA:
BR44038;
BS455168;
BS455169
KEGG:
R01624
MetaCyc:
ACP-S-ACETYLTRANSFER-RXN
SABIO-RK:
1766
|
|
|
|
malonyl-[acyl-carrier_protein] + H+ <=> acetyl-[acyl-carrier_protein] + CO2
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
4.1.1.87
malonyl-S-ACP decarboxylase
4.1.1.M15
|
–
–
–
|
BM
|
| |
BRENDA:
BR48970
KEGG:
R09482
MetaCyc:
MALONYL-ACPDECARBOX-RXN
|
|
|
|
acetyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + acetate + H+
|
3.1.2.16
citrate-lyase deacetylase
|
–
|
M
|
| |
BRENDA:
BS358864
MetaCyc:
CITRATE-PRO-3S-LYASE-THIOLESTERASE-RXN
|
|
|
|
acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> [acyl-carrier_protein] + acetoacetyl-[acyl-carrier_protein] + CO2
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
MK
|
| |
BRENDA:
BS376191
KEGG:
R04355
MetaCyc:
3-OXOACYL-ACP-SYNTH-BASE-RXN
SABIO-RK:
4051
|
|
|
|
malonyl-[acyl-carrier_protein] + a_biotinyl-[protein] <=> acetyl-[acyl-carrier_protein] + a_carboxybiotinyl-[protein]
|
2.1.3.10
malonyl-S-ACP:biotin-protein carboxyltransferase
|
–
|
|
| |
BRENDA:
BR48963
KEGG:
R08936
|
|
|
|
acetyl-[acyl-carrier_protein] + malonate <=> malonyl-[acyl-carrier_protein] + acetate
|
2.3.1.187
acetyl-S-ACP:malonate ACP transferase
|
–
|
|
| |
BRENDA:
BR48965
KEGG:
R08944
|
|
|
|
ATP + acetate + [acyl-carrier_protein] <=> AMP + diphosphate + acetyl-[acyl-carrier_protein]
|
6.2.1.35
acetate---[acyl-carrier protein] ligase
|
–
|
|
| |
BRENDA:
BR48976
KEGG:
R09475
|
|
|
|
[acyl-carrier_protein] + acetate + ATP <=> acetyl-[acyl-carrier_protein] + diphosphate + AMP
|
6.2.1.22
[citrate (pro-3S)-lyase] ligase
|
–
|
M
|
| |
BRENDA:
BR74;
BS368967
KEGG:
R04449
MetaCyc:
CITC-RXN
SABIO-RK:
4134
|
|
|
|
[acyl-carrier_protein] + S-acetylphosphopantetheine <=> acetyl-[acyl-carrier_protein] + 4''-phosphopantetheine
|
2.3.1.49
deacetyl-[citrate-(pro-3S)-lyase] S-acetyltransferase
|
–
|
M
|
| |
MetaCyc:
2.3.1.49-RXN
|
|
|
|
citryl-holo_[citrate_lyase_acyl-carrier_protein] <=> oxaloacetate + acetyl-[acyl-carrier_protein] + H+
|
4.1.3.34
citryl-CoA lyase
|
–
|
M
|
| |
MetaCyc:
CITRYLY-RXN
|
|
|
|
citrate + acetyl-[acyl-carrier_protein] + H+ <=> citryl-holo_[citrate_lyase_acyl-carrier_protein] + acetate
|
2.8.3.10
citrate CoA-transferase
|
–
|
M
|
| |
MetaCyc:
CITTRANS-RXN
|
|
|
|
S-adenosyl-L-methionine + soluble_holo-[acyl-carrier_protein] + acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + NADPH + H+ <=> (3S,4R,6E,8R,9S)-3,9-dihydroxy-4,8-dimethyldec-6-enoyl-[acp] + CO2 + S-adenosyl-L-homocysteine + NADP+ + H2O + [acyl-carrier_protein]
|
2.3.1.M60
|
–
|
M
|
| |
MetaCyc:
RXN-19848
|
|
|
|
(5S,6S,7R,8R,10E,12R,13S)-5,6,7,13-tetrahydroxy-8,12-dimethyl-3-oxotetradec-10-enoyl-[acp] + acetyl-[acyl-carrier_protein] + H2O <=> (5S,6S,7R,8R,10E,12R,13S)-3-(carboxymethyl)-3,5,6,7,13-pentahydroxy-8,12-dimethyltetradec-10-enoyl-[acp] + [acyl-carrier_protein] + H+
|
2.3.1.M62
|
–
|
M
|
| |
MetaCyc:
RXN-19850
|
|
|
|
acetyl-[acyl-carrier_protein] + H2O <=> soluble_holo-[acyl-carrier_protein] + acetate + H+
|
3.2.1.M21
|
–
|
|
| |
MetaCyc:
RXN-20501
|
|
|
|
acetyl-CoA + apo-acyl-carrier_protein <=> CoA + acetyl-[acyl-carrier_protein]
|
2.7.8.7
holo-[acyl-carrier-protein] synthase
|
–
|
|
| |
BRENDA:
BS359968
|
|
|
|
3-oxoacyl-ACP + acetyl-CoA <=> acetyl-[acyl-carrier_protein] + 3-oxoacyl-CoA
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
|
| |
BRENDA:
BS420004
|
|
|
|
acetoacetyl-[acyl-carrier_protein] + acetyl-CoA <=> acetyl-[acyl-carrier_protein] + acetoacetyl-CoA
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
|
| |
BRENDA:
BS420181
|
|
|
|
acetyl-[acyl-carrier_protein] + citrate <=> acetate + (3S)-citryl-[acyl-carrier_protein]
|
2.8.3.10
citrate CoA-transferase
|
–
|
|
| |
BRENDA:
BS358768
|
|
|
|
acetyl-[acyl-carrier_protein] + citramalate <=> citramalyl-[acyl-carrier_protein] + acetate
|
2.8.3.11
citramalate CoA-transferase
|
–
|
|
| |
BRENDA:
BS360572
|
|
|
|
(3S)-citryl-[acyl-carrier_protein] <=> acetyl-[acyl-carrier_protein] + oxaloacetate
|
4.1.3.34
citryl-CoA lyase
|
–
|
|
| |
BRENDA:
BS18560
|
|
|
|
acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> acetoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
|
|
| |
BRENDA:
BS320864
|
|
|
|
ATP + acetate + acetyl-[acyl-carrier_protein] <=> AMP + diphosphate + acetyl-[citrate_lyase]
|
6.2.1.22
[citrate (pro-3S)-lyase] ligase
|
–
|
|
| |
BRENDA:
BS453714
|
|
